Q15 / 90 · KVPY 2012 (SB/SX) · Chemistry
The C-O bond length in $\mathrm{CO}, \mathrm{CO}_{2}$ and $\mathrm{CO}_{3}{ }^{2-}$ follows the order -
- Correct answerA$\mathrm{CO} < \mathrm{CO}_{2} < \mathrm{CO}_{3}{ }^{2-}$
- B$\mathrm{CO}_{2} < \mathrm{CO}_{3}{ }^{2-} < \mathrm{CO}$
- C$\mathrm{CO}>\mathrm{CO}_{2}>\mathrm{CO}_{3}^{2-}$
- D$\mathrm{CO}_{3}{ }^{2-} < \mathrm{CO}_{2} < \mathrm{CO}$
Solution
Bond Length $\propto \frac{1}{\text { Bond Order }}$
$\mathrm{CO}, \mathrm{B} . \mathrm{O} .=3$
$\mathrm{O}=\mathrm{C}=\mathrm{O}, \mathrm{B} . \mathrm{O} .=2$


Hence, the correct answer is option: 'A'.