Q27 / 90 · KVPY 2010 (SB/SX) · Chemistry

The bond order in $\mathrm{O}_{2}{ }^{2-}$ is-

  • A
    2
  • B
    3
  • C
    $1.5$
  • Correct answer
    D
    1

Solution

Bond order of $\mathrm{O}_{2}{ }^{2-}$ Total electron $=18$ Configuration $=\mathrm{KK} \sigma(2 \mathrm{~s})^{2} \sigma^{*}(2 \mathrm{~s})^{2} \sigma\left(2 \mathrm{p}_{z}\right)^{2} \pi\left(2 \mathrm{p}_{x}\right)^{2} \pi\left(2 p_{y}\right)^{2} \pi^{*}\left(2 \mathrm{p}_{\mathrm{x}}\right)^{2} \pi^{*}\left(2 \mathrm{p}_{y}\right)^{2}$ Bond order $=\frac{\mathrm{N}_{\mathrm{b}}-\mathrm{N}_{\mathrm{a}}}{2}=\frac{8-6}{2}=1.0$

Hence, the correct answer is option: 'D'.

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