Q2 / 90 · JEE Main 2023 (12 Apr Shift 1) · Chemistry

The bond order and magnetic property of acetylide ion are same as that of

  • A
    O2+
  • B
    N2+
  • Correct answer
    C
    NO+
  • D
    O2-

Solution

The bond order of the acetylide ion HC≡C- is 3, indicating a triple bond between the carbon atoms.

The acetylide ion consists of two carbon atoms with a triple bond between them and a negative charge. In the triple bond, there are six bonding electrons (two pi bonds and one sigma bond) and zero antibonding electrons.

Among the given options NO+ will have the same bond order and magnetic property like acetylide ion.

Species Bond Order Magnetic moment
HC≡C- 3 0
O2+ 2.5 3 B.M
N2+ 2.5 3 B.M
NO+ 3 0
O2- 1.5 3 B.M

Hence, the correct answer is option: 'C'.

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