Q3 / 180 · KCET 2020 · Chemistry

Sulphide ore on roasting gives a gas $X . X$ reacts with $\mathrm{Cl}_{2}$ in the presence of activated charcoal to give $Y$. $Y$ is

  • Correct answer
    A
    $\mathrm{SO}_{2} \mathrm{Cl}_{2}$
  • B
    $\mathrm{S}_{2} \mathrm{Cl}_{2}$
  • C
    $\mathrm{SCl}_{6}$
  • D
    $\mathrm{SOCl}_{2}$

Solution

When sulphite ore is roasted it means that sulphide ore is being heated in the presence of excess of air to form a gas $\mathrm{SO}_{2}$. $\underset{\text { From sulphide ore) }}{\mathrm{S}}+\mathrm{O}_{2} \longrightarrow \underset{(X)}{\mathrm{SO}_{2}}$ e.g. $\quad 2 \mathrm{ZnS}+3 \mathrm{O}_{2} \longrightarrow 2 \mathrm{ZnO}+2 \mathrm{SO}_{2}$ Thereafter, $X$ reacts with $\mathrm{Cl}_{2}$ in the presence of activated charcoal to give $Y$
Figure

Hence, the correct answer is option: 'A'.

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