Q92 / 180 · NEET 2013 (Karnataka) · Chemistry
Some reaction of amines are given. Which one is not correct?
- Correct answerA

- B\(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_4+\mathrm{HNO}_2 \rightarrow \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}+\mathrm{N}_2\)
- C$\mathrm{CH}_3 \mathrm{NH}_2+\mathrm{C}_6 \mathrm{H}_5 \mathrm{SO}_2 \mathrm{Cl} \rightarrow \mathrm{CH}_3 \mathrm{NHSO}_2 \mathrm{C}_6 \mathrm{H}_5$
- D\(\left(\mathrm{CH}_3\right)_2 \mathrm{NH}+\mathrm{NaNO}_2+\mathrm{HCl} \rightarrow \left(\mathrm{CH}_3\right)_2 \quad \mathrm{~N}-\mathrm{N}=0\)
Solution
When aromatic tertiary anines undergo electrophilic substitution with nitrosonium ion to form green coloured p-nitrosoamines
Hence, the correct answer is option: 'A'.