Q29 / 170 · Manipal (MET) 2018 · Chemistry
Reimer-Tiemann reaction involves
- Acarbonium ion intermediate
- Correct answerBcarbene intermediate
- Ccarbanion intermediate
- Dfree radical intermediate
Solution
In the Reimer-Tiemann reaction carbene intermediate is formed
\(\mathrm{CHCl}_3+\mathrm{OH}^{-} \longrightarrow \mathrm{H}_2 \mathrm{O}+\mathrm{CCl}_3^{-} \longrightarrow \mathrm{Cl}^{-}+ \underset{\text{Dichlorocarbene}}{: \mathrm{CCl}_2}\)


Hence, the correct answer is option: 'B'.