Q29 / 170 · Manipal (MET) 2018 · Chemistry

Reimer-Tiemann reaction involves

  • A
    carbonium ion intermediate
  • Correct answer
    B
    carbene intermediate
  • C
    carbanion intermediate
  • D
    free radical intermediate

Solution

In the Reimer-Tiemann reaction carbene intermediate is formed \(\mathrm{CHCl}_3+\mathrm{OH}^{-} \longrightarrow \mathrm{H}_2 \mathrm{O}+\mathrm{CCl}_3^{-} \longrightarrow \mathrm{Cl}^{-}+ \underset{\text{Dichlorocarbene}}{: \mathrm{CCl}_2}\) Figure

Hence, the correct answer is option: 'B'.

More Alcohols Phenols and Ethers Questions