Q86 / 200 · NEET 2002 · Chemistry

$n$-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?

  • A
    $\mathrm{PCl}_5$
  • B
    Reduction
  • Correct answer
    C
    Oxidation with potassium dichromate
  • D
    Ozonolysis

Solution

Isopropyl alcohol and n-propyl alcohol can be chemically distinguished by oxidation with potassium dichromate.n-propyl alcohol on oxidation with potassium dichromate gives an aldehyde. Isopropyl alcohol on oxidation with potassium dichromate gives a ketone. During oxidation of potassium dichromate, solution of potassium dichromate turns bluegreen in the reactions. For isopropyl alcohol this colour change is fast and for $n$-propyl alcohol the colour change is slow. Figure Isopropyl alcohol and n-propyl alcohol are examples of position isomers.In isopropyl alcohol, the hydroxyl group is present in the second carbon atom whereas in n-propyl alcohol the hydroxyl group is present in the first carbon atom.

Hence, the correct answer is option: 'C'.

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