Q18 / 66 · JEE Advanced 2007 (Paper 2) · Chemistry

Paragraph: Reimer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.Figure
Question: The electrophile in this reaction is

  • A
    : CHCL
  • B
    ${ }^{+} \mathrm{CHCl}_2$
  • Correct answer
    C
    $: \mathrm{CCl}_2$
  • D
    $\cdot \mathrm{CCl}_3$

Solution

In Reimer-Tiemann reaction Figure

Hence, the correct answer is option: 'C'.

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