Q26 / 160 · TS EAMCET 2017 · Chemistry

Optically active Figure
was found to have lost its optical activity after standing in water containing a few drops of acids, mainly due to the formation of

  • A
    $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}=\mathrm{CH}_2$
  • Correct answer
    B
    $\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_3$
  • C
    Figure
  • D
    $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{OH}$

Solution

Figure
Figure
The above optically active compound undergo dehydration with few drops of acid and form stable alkene through the formation of stable carbocation.

Hence, the correct answer is option: 'B'.

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