Q22 / 90 · KVPY 2011 (SB/SX) · Chemistry

Optically active (S)-\alpha-methoxyacetaldehyde on reaction with MeMgX gave a mixture of alcohols. The major diastereomer ' $\mathrm{P}^{\prime}$ on treatment with $\mathrm{MeI} / \mathrm{K}_{2} \mathrm{CO}_{3}$ gave an optically inactive compound. P is- Figure
Figure
Figure

  • A
    i
  • B
    ii
  • C
    iii
  • Correct answer
    D
    none of these

Solution

Incorrect question The statement optically active (s) $-\alpha-$ methoxy acetaldehyde is incorrect.

Hence, the correct answer is option: 'D'.

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