Q11 / 51 · JEE Advanced 2023 (Paper 1) · Chemistry

One mole of an ideal monoatomic gas undergoes two reversible processes (A→B and B→C) as shown in the given figure:

Figure

A→B is an adiabatic process. If the total heat absorbed in the entire process (A→B and B→C) is RT2ln10, the value of 2logV3 is
[Use molar heat capacity of the gas at constant pressure, Cp,m=52R]

Correct answer: 7

Solution

qA→C=RT2ln10

qA→B=0                               (∵ adiabatic) 

qA→C=qA→B+qB→C

qA→C=qB→C

qA→c=nRT2lnV3 V2     ...(i)

For B→C
ΔE=q+w

ΔE=0                  (since isothermic)

q=-w

=--nRT2lnV3 V2

=nRT2lnV3 V2

qB→C=nRT2lnV3 V2

qB→C=RT2ln⁡V3V2          [Since n =1]

From A→B
T1 V1γ-1=T2 V2γ-1

600 V1γ-1=60 V2γ-1

10×1053-1=V2γ-1

105/3=V253-1

105/3=V22/3

V2=1053×32=1052

V2=1052    ...(2)
From equation (1)
qA→C=nRT2lnV3V2
Given, qA→C=RT2ln10

RT2ln10=RT2lnV3 V2

ln10=lnV3V2

ln10=lnV31052

10=V31052

V3=101+52=1072

2logV3=2log107/2=7

Hence, the correct answer is 7.

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