Q65 / 160 · JIPMER 2013 · Chemistry
On addition of conc. $\mathrm{H}_2 \mathrm{SO}_4$ to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet
- A$\mathrm{H}_2 \mathrm{SO}_4$ reduces HI to $I_2$
- BHI is of violet colour
- Correct answerCHI gets oxidised to $\mathrm{I}_2$
- DHI changes to $\mathrm{HIO}_3$
Solution
HI being a stronger reducing agent than $\mathrm{H}_2 \mathrm{SO}_4$, reduces $\mathrm{H}_2 \mathrm{SO}_4$ to $\mathrm{SO}_2$ and is itself oxidised to $I_2$.
Hence, the correct answer is option: 'C'.