Q65 / 160 · JIPMER 2013 · Chemistry

On addition of conc. $\mathrm{H}_2 \mathrm{SO}_4$ to a chloride salt, colourless fumes are evolved but in case of iodide salt, violet

  • A
    $\mathrm{H}_2 \mathrm{SO}_4$ reduces HI to $I_2$
  • B
    HI is of violet colour
  • Correct answer
    C
    HI gets oxidised to $\mathrm{I}_2$
  • D
    HI changes to $\mathrm{HIO}_3$

Solution

HI being a stronger reducing agent than $\mathrm{H}_2 \mathrm{SO}_4$, reduces $\mathrm{H}_2 \mathrm{SO}_4$ to $\mathrm{SO}_2$ and is itself oxidised to $I_2$.

Hence, the correct answer is option: 'C'.

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