Q23 / 180 · KCET 2015 · Chemistry
Number of possible alkynes with formula \( \mathrm{C}_{5} \mathrm{H}_{8} \) is
- A\( 12 \)
- Correct answerB\( 13 \)
- C\( 04 \)
- D\( 05 \)
Solution
There are only three isomers possible with formula \( \mathrm{CH}_{5} \mathrm{H}_{8} \) having structure:
(I) \( \mathrm{CH} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \)
(II) \( \mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \)
(III) \( \mathrm{CH} \equiv \mathrm{C}-\underset{\mathrm{CH}_{3}}{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3} \)
(I) \( \mathrm{CH} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \)
(II) \( \mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{3} \)
(III) \( \mathrm{CH} \equiv \mathrm{C}-\underset{\mathrm{CH}_{3}}{\mathrm{C}} \mathrm{H}-\mathrm{CH}_{3} \)
Hence, the correct answer is option: 'B'.