Q82 / 180 · AIIMS 2006 · Chemistry

Nitrobenzene on treatment with zinc dust and aqueous ammonium chloride gives

  • A
    $\mathrm{C}_6 \mathrm{H}_5 \mathrm{~N}=\mathrm{N}-\mathrm{C}_6 \mathrm{H}_5$
  • B
    $\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2$
  • C
    $\mathrm{C}_6 \mathrm{H}_5 \mathrm{NO}$
  • Correct answer
    D
    $\mathrm{C}_6 \mathrm{H}_5 \mathrm{NHOH}$.

Solution

When reduced with a neutral reducing agent like zinc dust and aqueous ammonium chloride, nitrobenzene gives phenyl hydroxyl amine. Figure

Hence, the correct answer is option: 'D'.

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