Q34 / 155 · WBJEE 2023 · Chemistry
Nickel combines with a uninegative monodentate ligand \(\left(\mathrm{X}^{-}\right)\)to form a paramagnetic complex \(\left[\mathrm{NiX}_4\right]^{2-}\). The hybridisation involved and number of unpaired electrons present in the complex are respectively.
- Correct answerA\(\mathrm{sp}^3\) two
- B\(\mathrm{dsp}^2\), zero
- C\(\mathrm{dsp}^2\), one
- D\(\mathrm{sp}^3\), one
Solution
Hint : \(\mathrm{Ni}^{2+}\left(\mathrm{d}^8\right)\)

it should be paramagnetic with 2 unpaired electrons

it should be paramagnetic with 2 unpaired electrons
Hence, the correct answer is option: 'A'.