Q34 / 155 · WBJEE 2023 · Chemistry

Nickel combines with a uninegative monodentate ligand \(\left(\mathrm{X}^{-}\right)\)to form a paramagnetic complex \(\left[\mathrm{NiX}_4\right]^{2-}\). The hybridisation involved and number of unpaired electrons present in the complex are respectively.

  • Correct answer
    A
    \(\mathrm{sp}^3\) two
  • B
    \(\mathrm{dsp}^2\), zero
  • C
    \(\mathrm{dsp}^2\), one
  • D
    \(\mathrm{sp}^3\), one

Solution

Hint : \(\mathrm{Ni}^{2+}\left(\mathrm{d}^8\right)\) Figure
it should be paramagnetic with 2 unpaired electrons

Hence, the correct answer is option: 'A'.

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