Q31 / 160 · TS EAMCET 2019 (04 May Shift 2) · Chemistry
Match the following:

The correct answer is

The correct answer is

- Correct answerA(a)
- B(b)
- C(c)
- D(d)
Solution
$\mathrm{V}^{4+}, \mathrm{Ti}^{3+}$ and $\mathrm{Ni}^{2+}$ having unpaired electrons in $d$-subshell. Therefore, there ions show $d$ - $d$ transition and form different colours. $\mathrm{Ti}^{4+}$ does not have unpaired electrons therefore, it is colourless.
\begin{array}{llll}
\hline & lons & & \multicolumn{1}{c}{\begin{array}{c}
Colour \\
(\mathrm{d}-\mathrm{d} transition )
\end{array}} \\
\hline (A) & \mathrm{V}^{4+} & (\mathrm{IV}) & Blue colour \\
\hline (B) & \mathrm{Ti}^{3+} & (\mathrm{II}) & Purple \\
\hline (C) & \mathrm{Ti}^{4+} & (I) & Colourless \\
\hline (D) & \mathrm{Ni}^{2+} & (III) & Green \\
\hline
\end{array}
Thus, option (1) is correct.
Hence, the correct answer is option: 'A'.