Q31 / 160 · TS EAMCET 2021 (04 Aug Shift 1) · Chemistry

Match the following
Column-1
Reaction
Column-2
Main product
A) 4FeCl3+3 K4Fe(CN)6→ I) Fe4Fe(CN)63
B) ZnCl2+4NaOH→ II) FeCl2
C) 2FeCl3+H2S→ III) Zn(OH)Cl
    IV) Fe3Fe(CN)63
    V) Na2ZnO2
    VI) FeS

  • A
    A B C
    I III VI
  • Correct answer
    B
    A B C
    I V II
  • C
    A B C
    IV V II
  • D
    A B C
    IV III VI

Solution

The ferric chloride reacts with the  K4Fe(CN)6 and gives the ion exchange reaction and formed the compound Fe4Fe(CN)63  and potassium chloride.

4FeCl3+3 K4Fe(CN)6→Fe4Fe(CN)63 +4KCl

Zinc chloride reacts with the sodium hydroxide and formed the Na2ZnO2 as a product.

In this reaction, the ferric chloride is reduced into ferrous chloride.

2FeCl3+H2S→2FeCl2 +S +2HCl

 

 

Hence, the correct answer is option: 'B'.

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