Q4 / 90 · JEE Main 2022 (27 Jun Shift 1) · Chemistry

Match List - I with List - II.

  List-I   List-II
A Lyophilic colloid I Liquid-liquid colloid
B Emulsion II Protective colloid
C Positively charged colloid III FeCl3+NaOH
D Negatively charged colloid IV FeCl3+ hot water

Choose the correct answer from the options given below

  • Correct answer
    A
    A-II,B-I,C-IV,D-III
  • B
    A-III,B-I,C-IV,D-II
  • C
    A-II,B-I,C-III,D-IV
  • D
    A-III,B-II,C-I,D-IV

Solution

Lyophilic colloids are stable due to charge and solvation, they can be used to protect Lyophobic colloids

Emulsions are liquid-liquid type of colloids

If FeCl3 is added to the excess of hot water, a positively charged sol of hydrated ferric oxide is formed due to adsorption of Fe3+ ions. However, when ferric chloride is added to NaOH solution, a negatively charged sol is obtained with adsorption of OH- ions.

Fe2O3·xH2O/Fe3+
Positively charged

FeOH3/OH-
Negatively charged

Hence, the correct answer is option: 'A'.

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