Q48 / 48 · JEE Advanced 2025 (Paper 1) · Physics

List-I shows various functional dependencies of energy $(E)$ on the atomic number $(Z)$. Energies associated with certain phenomena are given in List-II.\nChoose the option that describes the correct match between the entries in List-I to those in List-II.
List-I List-II
$(P)$ $E \\propto Z^2$ $(1)$ energy of characteristic x-rays
$(Q)$ $E \\propto(Z-1)^2$ $(2)$ electrostatic part of the nuclear binding energy for stable nuclei with mass numbers in the range 30 to 170
$(R)$ $E \\propto Z(Z-1)$ $(3)$ energy of continuous x-rays
$(S)$ $E$ is practically independent of $Z$ $(4)$ average nuclear binding energy per nucleon for stable nuclei with mass number in the range 30 to 170
$(5)$ energy of radiation due to electronic transitions from hydrogen-like atoms

  • A
    $\mathrm{P} \rightarrow 4, \mathrm{Q} \rightarrow 3, \mathrm{R} \rightarrow 1, \mathrm{~S} \rightarrow 2$
  • B
    $\mathrm{P} \rightarrow 5, \mathrm{Q} \rightarrow 2, \mathrm{R} \rightarrow 1, \mathrm{~S} \rightarrow 4$
  • Correct answer
    C
    $\mathrm{P} \rightarrow 5, \mathrm{Q} \rightarrow 1, \mathrm{R} \rightarrow 2, \mathrm{~S} \rightarrow 4$
  • D
    $\mathrm{P} \rightarrow 3, \mathrm{Q} \rightarrow 2, \mathrm{R} \rightarrow 1, \mathrm{~S} \rightarrow 5$

Solution

(P) Energy of H -like atom is $\begin{aligned} & \mathrm{E}=-13.6 \frac{\mathrm{Z}^2}{\mathrm{n}^2} \text { So } \\ & \mathrm{E} \propto \mathrm{Z}^2 \\ & \mathrm{P} \rightarrow(5)\end{aligned}$ (Q) Energy of characteristic X-ray by moseley's correction $\begin{aligned} & E=-13.6(Z-1)^2\left[\frac{1}{n_1^2}-\frac{1}{n_2^2}\right] \text { So } \\ & E \propto(Z-1)^2 \\ & Q \rightarrow(1)\end{aligned}$ (R) Electrostatics binding energy is proportional to $Z(Z-1)$ $R \rightarrow(2)$ (S) For stable nuclei with mass no. in range 30 to 170 . Binding energy per nucleon is constant \& graph is straight line $S \rightarrow(4)$ Ans. (C) is correct

Hence, the correct answer is option: 'C'.

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