Q25 / 90 · JEE Main 2013 (22 Apr Online) · Chemistry

In Williamson synthesis of mixed ether having a primary and a tertiary alkyl group if tertiary halide is used, then :

  • A
    Rate of reaction will be slow due to slow cleavage of carbon-halogen bond.
  • Correct answer
    B
    Alkene will be the main product.
  • C
    Simple ether will form instead of mixed ether.
  • D
    Expected mixed ether will be formed.

Solution

The tertiary alkyl halide undergo elimination reaction to give alkenes Figure
Figure

Hence, the correct answer is option: 'B'.

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