Q11 / 100 · BITSAT 2024 (Memory Based Paper 2) · Chemistry

In the Victor-Meyer's test, the colour given by $1^{\circ} .2^{\circ}$ and $3^{\circ}$ alcohols are respectively:

  • A
    Red, colourless, blue
  • Correct answer
    B
    Red, blue, colourless
  • C
    Colourless, red, blue
  • D
    Red, blue, violet

Solution

Victor Meyer's test: The various steps involved are (i)$\mathrm{RCH}_2 \mathrm{OH} \xrightarrow{\mathrm{HI}} \mathrm{RCH}_2 \mathrm{I} \xrightarrow{\mathrm{AgNO}_2} \mathrm{RCH}_2 \mathrm{NO}_2$ Figure (ii)Figure
Figure (iii) $\mathrm{R}_3 \mathrm{COH} \xrightarrow{\mathrm{HI}} \mathrm{R}_3 \mathrm{CI} \xrightarrow{\mathrm{AgNO}_2} \mathrm{R}_3 \mathrm{CNO}_2$ $-\xrightarrow{\mathrm{HNO}_2}$ No reaction $\xrightarrow{\mathrm{KOH}}$ Colourless

Hence, the correct answer is option: 'B'.

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