Q11 / 100 · BITSAT 2024 (Memory Based Paper 2) · Chemistry
In the Victor-Meyer's test, the colour given by $1^{\circ} .2^{\circ}$ and $3^{\circ}$ alcohols are respectively:
- ARed, colourless, blue
- Correct answerBRed, blue, colourless
- CColourless, red, blue
- DRed, blue, violet
Solution
Victor Meyer's test: The various steps involved are
(i)$\mathrm{RCH}_2 \mathrm{OH} \xrightarrow{\mathrm{HI}} \mathrm{RCH}_2 \mathrm{I} \xrightarrow{\mathrm{AgNO}_2} \mathrm{RCH}_2 \mathrm{NO}_2$
(ii)
(iii)
$\mathrm{R}_3 \mathrm{COH} \xrightarrow{\mathrm{HI}} \mathrm{R}_3 \mathrm{CI} \xrightarrow{\mathrm{AgNO}_2} \mathrm{R}_3 \mathrm{CNO}_2$
$-\xrightarrow{\mathrm{HNO}_2}$ No reaction $\xrightarrow{\mathrm{KOH}}$ Colourless
(ii)
(iii)
$\mathrm{R}_3 \mathrm{COH} \xrightarrow{\mathrm{HI}} \mathrm{R}_3 \mathrm{CI} \xrightarrow{\mathrm{AgNO}_2} \mathrm{R}_3 \mathrm{CNO}_2$
$-\xrightarrow{\mathrm{HNO}_2}$ No reaction $\xrightarrow{\mathrm{KOH}}$ ColourlessHence, the correct answer is option: 'B'.