Q69 / 180 · NEET 2013 (All India) · Chemistry

In the reaction, Figure
$A$ is

  • A
    $\mathrm{HgSO}_4 / \mathrm{H}_2 \mathrm{SO}_4$
  • B
    $\mathrm{Cu}_2 \mathrm{Cl}_2$
  • Correct answer
    C
    $\mathrm{H}_3 \mathrm{PO}_2$ and $\mathrm{H}_2 \mathrm{O}$
  • D
    $\mathrm{H}^{+} / \mathrm{H}_2 \mathrm{O}$

Solution

When diazonium salt is treated with $\mathrm{H}_3 \mathrm{PO}_2$ followed by hydrolysis, it diazonium group is replaced by $-\mathrm{H}$ resulting to the formation of hydrocarbon. Thus, $A$ must be $\mathrm{H}_3 \mathrm{PO}_2 / \mathrm{H}_2 \mathrm{O}$. Figure

Hence, the correct answer is option: 'C'.

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