Q69 / 180 · NEET 2013 (All India) · Chemistry
In the reaction,

$A$ is

$A$ is
- A$\mathrm{HgSO}_4 / \mathrm{H}_2 \mathrm{SO}_4$
- B$\mathrm{Cu}_2 \mathrm{Cl}_2$
- Correct answerC$\mathrm{H}_3 \mathrm{PO}_2$ and $\mathrm{H}_2 \mathrm{O}$
- D$\mathrm{H}^{+} / \mathrm{H}_2 \mathrm{O}$
Solution
When diazonium salt is treated with $\mathrm{H}_3 \mathrm{PO}_2$ followed by hydrolysis, it diazonium group is replaced by $-\mathrm{H}$ resulting to the formation of hydrocarbon. Thus, $A$ must be $\mathrm{H}_3 \mathrm{PO}_2 / \mathrm{H}_2 \mathrm{O}$.


Hence, the correct answer is option: 'C'.