Q11 / 120 · VITEEE 2007 · Chemistry
In $\mathrm{TeCl}_{4}$ the central atom tellurium involves
- A$\mathrm{sp}^{3}$ hybridization
- Correct answerBsp ${ }^{3}$ d hybridization
- C$\mathrm{sp}^{3} \mathrm{~d}^{2}$ hybridization
- Dds$p^{ 2}$ hybridization
Solution
Hybridisation $=\frac{1}{2}$ [Number of valence electrons of central atom $+$ no. of monovalent atoms attached to it $+$ negative charge if any $-$ positive charge if any]
$\begin{array}{l}
=\frac{1}{2}[6+4+0-0]=5=\mathrm{sp}^{3} \mathrm{~d} \\
{\left[\because \mathrm{Te}(52)=[\mathrm{Kr}] 4 \mathrm{~d}^{10} 5 \mathrm{~s}^{2} 5 \mathrm{p}^{4}\right]}
\end{array}$
Hence, the correct answer is option: 'B'.