In polymer Buna-$\mathrm{S}:\text{'}\mathrm{S}\text{'}$ stands for:

Buna--$\mathrm{S}$, $\text{'}\mathrm{S}\text{'}$ stand for styrene.

Buna – S is a more commonly used name for a polymer named styrene butadiene rubber. The structure of Buna – S is given by:

Buna – S is formed using the monomers butadiene and styrene.

Thus in Buna – S, the Bu stands for Butadiene, since butadiene is one of the constituent monomers of the given polymer. Also, Na stands for sodium and S represents the monomer Styrene used for the synthesis of the given polymer.