Q144 / 150 · MHT CET 2025 (26 Apr Shift 1) · Physics
In Paschen series, wavelength of first line is ' $\lambda_1$ ' and for Brackett series, wavelength of first line is ' $\lambda_2$ ' then ratio $\frac{\lambda_1}{\lambda_2}$ is
- A$\frac{7}{400}$
- B$\frac{9}{144}$
- Correct answerC$\frac{81}{175}$
- D$\frac{108}{509}$
Solution
The Rydberg formula gives the wavelength of spectral lines as
$\frac{1}{\lambda} = R \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right)$
where $R$ is the Rydberg constant and $n_i > n_f$.For the first line of the Paschen series ($n_f = 3$, $n_i = 4$):
$\frac{1}{\lambda_1} = R \left( \frac{1}{9} - \frac{1}{16} \right) = R \left( \frac{7}{144} \right)$
Hence $\lambda_1 = \frac{144}{7R}$.
For the first line of the Brackett series ($n_f = 4$, $n_i = 5$):
$\frac{1}{\lambda_2} = R \left( \frac{1}{16} - \frac{1}{25} \right) = R \left( \frac{9}{400} \right)$
Thus $\lambda_2 = \frac{400}{9R}$.
The ratio becomes
$\frac{\lambda_1}{\lambda_2} = \frac{144}{7R} \times \frac{9R}{400} = \frac{1296}{2800}$
Simplifying by dividing numerator and denominator by 16 yields $\frac{81}{175}$.
This corresponds to option C.
Hence, the correct answer is option: 'C'.