Q82 / 180 · AIIMS 2009 · Chemistry
In Oppenauer's oxidation,
- Asecondary alcohol is oxidised to carboxylic acid in acetone solvent using aluminium tertiary butoxide
- Bsecondary alcohol is oxidised to carboxylic acid without affecting the $\mathrm{C}=\mathrm{C}$ or $\mathrm{C} \equiv \mathrm{C}$ bond by aluminium tertiary butoxide in acetone solvent
- Correct answerCsecondary alcohol is oxidised to ketone without affecting $\mathrm{C}=\mathrm{C}$ or $\mathrm{C} \equiv \mathrm{C}$ bond by aluminium tertiary butoxide
- Dsecondary alcohol is oxidised to ketone by chromic acid - pyridine complex.
Solution
In Oppenauer's oxidation, secondary alcohol is oxidised to corresponding ketone in the presence of aluminium tertiary butoxide. Other oxidisable groups are not affected.


Hence, the correct answer is option: 'C'.