Q32 / 68 · NEST (NISER) 2023 (Session 2) · Chemistry

In an electrophilic addition reaction of olefins, the stability of carbocations plays a crucial role. Consider the compounds $\mathbf{P}$ and $\mathbf{Q}$ that can undergo such reactions with different reagents.
Figure

With reference to the above reactions, the correct statement(s) is(are):

  • A
    In the HBr addition, the rate of the reaction is faster for $\mathbf{Q}$ than for $\mathbf{P}$.
  • Correct answer
    B
    HBr addition to P gives an equal mixture of enantiomers as a major product.
  • C
    P reacts with diborane followed by oxidation with $\mathrm{H}_2 \mathrm{O}_2 / \mathrm{NaOH}$ gives racemic alcohol as a major product.
  • Correct answer
    D
    Reaction of $\mathbf{P}$ with $\mathrm{O}_3$ followed by treatment with $\mathrm{Zn} / \mathrm{H}_2 \mathrm{O}$ gives methyl formate and formaldehyde.

Hence, the correct answer is options: 'B', 'D'.

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