Q38 / 180 · COMEDK 2025 (25 May Shift) · Chemistry
In alkaline medium, $I^{-}$is oxidised to ' X ' by $\mathrm{KMnO}_4$. The oxidation state of iodine in ' X ' is:
- A+7
- B0
- Correct answerC+5
- D+3
Solution
In alkaline medium, the reaction between permanganate ion and iodide ion is given by the balanced chemical equation:
2MnO$_{4}^{-}$ + I$^{-}$ + H$_{2}$O $\rightarrow$ 2MnO$_{2}$ + IO$_{3}^{-}$ + 2OH$^{-}$
The product 'X' formed by the oxidation of I$^{-}$ is the iodate ion, IO$_{3}^{-}$.
To find the oxidation state of iodine in IO$_{3}^{-}$, let the oxidation state be $x$.
$x + 3(-2) = -1$
$x - 6 = -1$
$x = +5$
Therefore, the oxidation state of iodine in 'X' is +5.
Answer: +5
2MnO$_{4}^{-}$ + I$^{-}$ + H$_{2}$O $\rightarrow$ 2MnO$_{2}$ + IO$_{3}^{-}$ + 2OH$^{-}$
The product 'X' formed by the oxidation of I$^{-}$ is the iodate ion, IO$_{3}^{-}$.
To find the oxidation state of iodine in IO$_{3}^{-}$, let the oxidation state be $x$.
$x + 3(-2) = -1$
$x - 6 = -1$
$x = +5$
Therefore, the oxidation state of iodine in 'X' is +5.
Answer: +5
Hence, the correct answer is option: 'C'.