Q139 / 160 · AP EAMCET 2019 (20 Apr Shift 2) · Physics
If the speed of sound in a mixture of 2 moles of Helium and 2 moles of Hydrogen at temperature $\frac{972}{5} \mathrm{~K}$ is $n \times 100 \mathrm{~ms}^{-1}$, then the value of $n$ is (Take, $\left.R=\frac{25}{3} \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\right)$
- Correct answerA9
- B10
- C100
- D90
Solution
Given, $T=\frac{972}{5} \mathrm{~K}, R=\frac{25}{3} \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$
Molecular mass of the mixture
$$
\begin{aligned}
& \quad=\frac{n_{\mathrm{He}} M_{\mathrm{He}}+n_H M_H}{n_{\mathrm{He}}+n_H} \\
& \because n_{\mathrm{He}}=2 \text { moles, } n_H=2 \text { moles } \\
& M_{\mathrm{He}}=4, M_H=2
\end{aligned}
$$
$\therefore$ Molecular mass of the mixtures,
$$
\begin{aligned}
M & =\frac{2 \times 4+2 \times 2}{2+2} \\
& =\frac{8+4}{4}=3 \mathrm{gm} / \mathrm{mole}
\end{aligned}
$$
$\because$ Degree of freedom of mixture
$$
\begin{aligned}
f=\frac{2 \times 3+2 \times 5}{2+2} & =4 \\
\because \quad f_{\text {mix }}=1+\frac{2}{f} & =1.5 \\
\because \text { Speed of sound } & =\sqrt{\frac{f_{\text {mix }} R T}{M}} \\
& =\sqrt{\frac{1.5 \times \frac{25}{3} \times \frac{972}{5}}{3 \times 10^{-3}}} \\
& =900=n \times 100 \mathrm{~m} / \mathrm{s}
\end{aligned}
$$
Hence, $n=9$
Hence, the correct answer is option: 'A'.