Q111 / 150 · MHT CET 2025 (19 Apr Shift 1) · Physics
If ' $\lambda_1$ ' and ' $\lambda_2$ ' are the wavelengths of the first member of the Balmer and Paschen series, in hydorgen atom respectively, then the ratio of respective frequencies, $f_1 / f_2$, is
- Correct answerA20:7
- B27:5
- C50:9
- D108:7
Solution
The ratio of frequencies $f_1/f_2$ for the first members of the Balmer and Paschen series in hydrogen is determined using the Rydberg formula:
$\frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_f^2} - \frac{1}{n_i^2} \right)$
For the Balmer series ($n_f = 2$), the first member corresponds to $n_i = 3$:
$\frac{1}{\lambda_1} = R \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = \frac{5R}{36}$
The frequency is $f_1 = c/\lambda_1 = 5Rc/36$.
For the Paschen series ($n_f = 3$), the first member corresponds to $n_i = 4$:
$\frac{1}{\lambda_2} = R \left( \frac{1}{3^2} - \frac{1}{4^2} \right) = \frac{7R}{144}$
The frequency is $f_2 = c/\lambda_2 = 7Rc/144$.
The ratio becomes:
$\frac{f_1}{f_2} = \frac{5Rc/36}{7Rc/144} = \frac{5}{36} \times \frac{144}{7} = \frac{20}{7}$
Final answer: $\boxed{20:7}$
Hence, the correct answer is option: 'A'.