Q24 / 160 · AP EAMCET 2021 (24 Aug Shift 2) · Chemistry

Identify the products $(P),(Q)$ and $(R)$ formed from the following reactions. Figure
Figure

  • Correct answer
    A
    $(P)$ : Benzene hexachloride $(Q)$ : Hexachlorobenzene $(R)$: Cyclohexanol
  • B
    $(P)$ : Hexachlorobenzene $(Q)$ : Benzene hexachloride $(R)$ : Cyclohexenol
  • C
    $(P)$ : Benzene hexachloride $(Q)$ : Hexachlorobenzene $(R)$ : Cyclohexane
  • D
    $(P)$ : Hexachlorobenzene $(Q)$ : Benzene hexachloride $(R)$ : Cyclohexane

Solution

The ring delocalisation is permanently broken and a chlorine atom adds on to each carbon atom and forms benzene hexachloride. Figure
Figure
Figure
So, $(P)=$ Benzene hexachloride $(Q)=$ Hexachlorobenzene $(R)=$ Cyclohexanol.

Hence, the correct answer is option: 'A'.

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