Q145 / 200 · MHT CET - Medical 2026 (25 April Shift 2) · Chemistry

Identify the product obtained when nitro alkanes are treated with Sn / HCl.

  • Correct answer
    A
    $\text{R-NH}_2$
  • B
    $\text{R}_2\text{NH}$
  • C
    $\text{R}_3\text{N}$
  • D
    $\text{R}_4\text{N}^+\text{X}^-$

Solution

Nitro alkanes are reduced to primary amines when treated with a mixture of tin and hydrochloric acid (Sn/HCl). The reaction involves the reduction of the nitro group ($-\text{NO}_2$) to an amino group ($-\text{NH}_2$).

$\text{R-NO}_2 + 6[\text{H}] \xrightarrow{\text{Sn/HCl}} \text{R-NH}_2 + 2\text{H}_2\text{O}$

Thus, the product obtained is a primary amine, $\text{R-NH}_2$.

Answer: $\text{R-NH}_2$

Hence, the correct answer is option: 'A'.

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