Q37 / 150 · MHT CET 2025 (19 Apr Shift 1) · Chemistry

Identify the product ' B ' in the following reaction sequence. $\text { Alkyl halide } \frac{\mathrm{Mg}}{\text { Dry ether }} \mathrm{A} \xrightarrow{\mathrm{NH}_3} \mathrm{~B}$

  • A
    Alkyl magnesium halide
  • B
    Alkyl amine
  • Correct answer
    C
    Hydrocarbon
  • D
    Alkyl nitrile

Solution

Reaction sequence analysis:

Alkyl halide $\mathrm{R-X}$ reacts with magnesium in dry ether to form Grignard reagent $\mathrm{A = R-Mg-X}$.

Grignard reagents are strong bases that react with compounds containing acidic protons. Ammonia $\mathrm{NH_3}$ has acidic hydrogens, producing the corresponding hydrocarbon via proton transfer: $\mathrm{R-Mg-X + H-NH_2 \rightarrow R-H + Mg(X)NH_2}$.

The product $\mathrm{B}$ is therefore a hydrocarbon $\mathrm{R-H}$.

Among the options, the correct answer corresponds to hydrocarbon: $\boxed{C}$.

Hence, the correct answer is option: 'C'.

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