Q33 / 150 · MHT CET 2026 (20 April Shift 1) · Chemistry

Identify the law for the statement "Overall the enthalpy change for a reaction is equal to sum of enthalpy changes of individual steps in the reaction"

  • A
    First law of thermodynamics
  • Correct answer
    B
    Hess's law
  • C
    Avogadro's law
  • D
    Second law of thermodynamics

Solution

Hess's law of constant heat summation states that the total enthalpy change for a chemical reaction is independent of the path by which the reaction occurs.

If a reaction takes place in several steps, the overall enthalpy change is equal to the sum of the enthalpy changes of the individual steps. This is because enthalpy is a state function, meaning it depends only on the initial and final states of the system, not on the path taken.

Answer: Hess's law

Hence, the correct answer is option: 'B'.

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