Q89 / 200 · NEET 2007 · Chemistry

Identify the incorrect statement among the following:

  • A
    Lanthanoid contraction is the accumulation of successive shrinkages
  • Correct answer
    B
    As a result of lanthanoid contraction, the properties of $4 d$ series of the transition elements have no similarities with the $5 d$ series of elements
  • C
    Shielding power of $4 f$ electrons is quite weak
  • D
    Thee is a decrease in the radii of the atoms or ions as one proceeds from La to $\mathrm{Lu}$

Solution

There is a steady decrease in the radii as the atomic number of the lanthanide elements increases. For every additional proton added in nucleus the corresponding electron goes to $4 f$ subshell. The shape of $f$-orbitals is very much diffused and they have poor shielding effect. The effective nuclear charge increases which causes the contraction in the size of electron charge cloud. This contraction in size is quite regular and known as Lanthanoid contraction. Since the change in the ionic radii in the lanthanide series is very small, thus their chemical properties are similar. Figure
Related Theory There is no regular trend in ionization potential in the group due to lanthanide contraction. Caution The lanthanide contraction is responsible because $\mathrm{Zr}$ and Hf have about the same radius

Hence, the correct answer is option: 'B'.

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