Q32 / 120 · VITEEE 2006 · Chemistry
Identify the correct statement
- AAldehydes on reduction give secondary alcohols
- BKetones on reduction give primary alcohols
- CKetones reduce Fehling's solution and give red cuprous oxide
- Correct answerDKetones do not react with alcohols
Solution
Ketones do not react with alcohol.
(i) Aldehydes reduction $\longrightarrow 1^{\circ}$ alcohol
e.g., $\mathrm{CH}_{3} \mathrm{CHO} \longrightarrow \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}$
(ii)

(iii) Ketones do not reduce Fehling solution but aldehydes do so.

(iii) Ketones do not reduce Fehling solution but aldehydes do so.
Hence, the correct answer is option: 'D'.