Q37 / 160 · AP EAMCET 2021 (25 Aug Shift 2) · Chemistry

Identify the compound (B) in given reaction. $\mathrm{CH}_3 \mathrm{Cl} \xrightarrow{\mathrm{KCN}}(A) \xrightarrow{\mathrm{H}^{+} / \mathrm{H}_2 \mathrm{O}}(B)$

  • A
    $\mathrm{CH}_3 \mathrm{NH}_2$
  • B
    $\mathrm{HCOOH}$
  • Correct answer
    C
    $\mathrm{CH}_3 \mathrm{COOH}$
  • D
    $\mathrm{CH}_3 \mathrm{COCH}_3$

Solution

When chloromethane reacts with potassium cyanide, it will produce methyl cyanide (A) and potassium chloride. It is a nucleophilic substitution reaction in which cyanide ion will displace chloride ion. On further step, methyl cyanide gets hydrolysed and give acetic acid (B). Figure

Hence, the correct answer is option: 'C'.

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