Q2 / 150 · MHT CET 2023 (13 May Shift 1) · Chemistry

Identify substrate ' $\mathrm{A}$ ' in the following conversion. $$ \mathrm{A}+\underset{\text { (excess) }}{\mathrm{CH}_3 \mathrm{I}} \stackrel{\Delta}{\longrightarrow} \mathrm{C}_2 \mathrm{H}_5\left(\mathrm{CH}_3\right)_3 \stackrel{+}{\mathrm{N} \mathrm{N}^{-}} $$

  • A
    $\mathrm{C}_2 \mathrm{H}_5 \mathrm{NO}_2$
  • B
    $\mathrm{C}_2 \mathrm{H}_5 \mathrm{CN}$
  • Correct answer
    C
    $\mathrm{C}_2 \mathrm{H}_5 \mathrm{NH}_2$
  • D
    $\mathrm{CH}_3 \mathrm{CONH}_2$

Solution

$$ \mathrm{C}_2 \mathrm{H}_5 \mathrm{NH}_2+\underset{\text { (excess) }}{\mathrm{CH}_3 \mathrm{I}} \stackrel{\Delta}{\longrightarrow} \underset{\text { Tetraalkylammonium iodide }}{\mathrm{C}_2 \mathrm{H}_5\left(\mathrm{CH}_3\right)_3 \mathrm{NI}^{-}} $$ The reaction is known as exhaustive alkylation of amines.

Hence, the correct answer is option: 'C'.

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