Q34 / 150 · MHT CET 2025 (21 Apr Shift 2) · Chemistry

Identify sequential reactions involved in Sol-Gel process .

  • A
    Poly condensation and hydorlysis
  • Correct answer
    B
    Hydrolysis and poly condensation
  • C
    Poly condensation and oxidation
  • D
    Oxidation and hydrolysis

Solution

The sol-gel process involves two sequential reactions for producing solid materials from molecular precursors.

Hydrolysis replaces alkoxy groups with hydroxyl groups:
$\mathrm{M(OR)_n + xH_2 O \rightarrow M(OH)_x(OR)_{n-x} + xROH}$

Polycondensation follows, forming metal-oxygen-metal bridges through either olation/oxolation or esterification:
$\mathrm{M-OH + HO-M \rightarrow M-O-M + H_2 O}$
$\mathrm{M-OR + HO-M \rightarrow M-O-M + ROH}$

This sequence establishes the correct order as hydrolysis followed by polycondensation, corresponding to option B.

Hence, the correct answer is option: 'B'.

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