Q3 / 150 · MHT CET 2025 (21 Apr Shift 1) · Chemistry
Identify product A in following reaction.
$\mathrm{C}_6 \mathrm{H}_5 \stackrel{+}{\mathrm{N}_2} \mathrm{Cl}^{-} \xrightarrow{\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}} \mathrm{~A}+\mathrm{N}_2+\mathrm{CH}_3 \mathrm{CHO}+\mathrm{HCl}$
- Correct answerA$\mathrm{C}_6 \mathrm{H}_6$
- B$\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2$
- C$\mathrm{C}_6 \mathrm{H}_5 \mathrm{COOH}$
- D$\mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl}$
Solution
Benzenediazonium chloride with ethanol undergoes reduction where the diazonium group is replaced by hydrogen.
The diazonium salt $\mathrm{C_6H_5\stackrel{+}{N_2}Cl^{-}}$ is electrophilic and ethanol acts as a reducing agent, donating hydrogen while being oxidized to acetaldehyde. Nitrogen gas evolves, and hydrochloric acid forms from the chloride ion.
The balanced reaction is:
$\mathrm{C_6H_5\stackrel{+}{N_2}Cl^{-}} + \mathrm{C_2H_5OH} \rightarrow \mathrm{C_6H_6} + \mathrm{N_2} + \mathrm{CH_3CHO} + \mathrm{HCl}$
Comparing with the given transformation, A is benzene $\mathrm{(C_6H_6)}$.
Final answer: $\boxed{\text{A}}$
Hence, the correct answer is option: 'A'.