Q135 / 200 · MHT CET - Medical 2026 (25 April Shift 1) · Chemistry

Identify Lucas reagent from following.

  • A
    conc. $\text{HCl}$ + anhydrous $\text{AlCl}_3$
  • Correct answer
    B
    conc. $\text{HCl}$ + anhydrous $\text{ZnCl}_2$
  • C
    conc. $\text{HCl}$ + dil. $\text{H}_2\text{SO}_4$
  • D
    conc. $\text{HCl}$ + conc. $\text{H}_2\text{SO}_4$

Solution

Lucas reagent is a mixture of concentrated hydrochloric acid ($\text{HCl}$) and anhydrous zinc chloride ($\text{ZnCl}_2$).

It is used in organic chemistry to differentiate between primary, secondary, and tertiary alcohols based on their reactivity and the time taken to form turbidity.

Answer: conc. $\text{HCl}$ + anhydrous $\text{ZnCl}_2$

Hence, the correct answer is option: 'B'.

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