Q22 / 66 · NTA Abhyas (JEE Main) 2020 · Chemistry · Carboxylic Acid Derivatives

Identify A and B in the reaction given below:

Ethane nitrile → aq .H 2 SO 4 Hydrolysis A → Sodalime Decarboxylation

  • Correct answer
    A
    Ethanoic acid, Methane
  • B
    Ethanoic acid, Ethane
  • C
    Acetone, Methane
  • D
    Acetic acid, Methanol

Solution

Alkyl cyanides are generally named as nitriles of acids which they produce on hydrolysis. The ending ic acid of common name of the acid is replaced by term nitrile and the letter 'O' is inserted in between. For example:

CH 3 −CN Acetonitrile → (H 2 O) CH 3 COOH Acetic acid

So, the compound (A) is Ethanoic acid.

CH 3 COOH Sodium acetate  +  NaOH Sodium Hydroxide → CaO Δ CH 4 Methane  +  Na 2 CO 3 Sodium carbonate

So, the compound (B) is Methane.

Hence, the correct answer is option: 'A'.

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