Q25 / 67 · NEST (NISER) 2022 (Session 2) · Chemistry

Hydrolysis of $\mathrm{PCl}_3$ in the presence of moisture gives the compound $\mathbf{X}$ along with fumes of HCl . On heating, $\mathbf{X}$ disproportionates to give compound $\mathbf{Y}$ and phosphine. On heating, $\mathbf{Y}$ gives compound $\mathbf{Z}$ and water. The correct statement is

  • A
    The oxidation states of phosphorus in $\mathbf{X}, \mathbf{Y}$ and $\mathbf{Z}$ are $+3,+4$ and +5 , respectively
  • Correct answer
    B
    $\text { The geometry around phosphorus in } \mathbf{X}, \mathbf{Y} \text { and } \mathbf{Z} \text { is tetrahedral. }$
  • C
    $\text { Among } \mathbf{X}, \mathbf{Y} \text { and } \mathbf{Z} \text {, the compounds } \mathbf{Y} \text { and } \mathbf{Z} \text { are reducing agents. }$
  • D
    $\text { The basicities of } \mathbf{X} \text { and } \mathbf{Y} \text { are same. }$

Hence, the correct answer is option: 'B'.

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