Q25 / 67 · NEST (NISER) 2022 (Session 2) · Chemistry
Hydrolysis of $\mathrm{PCl}_3$ in the presence of moisture gives the compound $\mathbf{X}$ along with fumes of HCl . On heating, $\mathbf{X}$ disproportionates to give compound $\mathbf{Y}$ and phosphine. On heating, $\mathbf{Y}$ gives compound $\mathbf{Z}$ and water. The correct statement is
- AThe oxidation states of phosphorus in $\mathbf{X}, \mathbf{Y}$ and $\mathbf{Z}$ are $+3,+4$ and +5 , respectively
- Correct answerB$\text { The geometry around phosphorus in } \mathbf{X}, \mathbf{Y} \text { and } \mathbf{Z} \text { is tetrahedral. }$
- C$\text { Among } \mathbf{X}, \mathbf{Y} \text { and } \mathbf{Z} \text {, the compounds } \mathbf{Y} \text { and } \mathbf{Z} \text { are reducing agents. }$
- D$\text { The basicities of } \mathbf{X} \text { and } \mathbf{Y} \text { are same. }$
Hence, the correct answer is option: 'B'.