Q79 / 180 · NEET 2025 · Chemistry

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) :Figure undergoes $\mathrm{S}_{\mathrm{N}} 2$ reaction faster thanFigure
Reason (R) : Iodine is a better leaving group because of its large size. In the light of the above statements, choose the correct answer from the options given below :

  • Correct answer
    A
    Both $\mathbf{A}$ and $\mathbf{R}$ are true and $\mathbf{R}$ is the correct explanation of $\mathbf{A}$.
  • B
    Both $\mathbf{A}$ and $\mathbf{R}$ are true but $\mathbf{R}$ is not the correct explanation of $\mathbf{A}$.
  • C
    $\mathbf{A}$ is true but $\mathbf{R}$ is false
  • D
    $\mathbf{A}$ is false but $\mathbf{R}$ is true

Solution

Rate of $\mathrm{S}_{\mathrm{N}} 2 \propto$ Leaving tendency of leaving group. Iodine is better L.G. than chlorine due to its bigger size.

Hence, the correct answer is option: 'A'.

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