Q83 / 200 · NEET 2023 (Manipur) · Chemistry

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : Ionisation enthalpies of early actinoids are lower than for early lanthanoids. Reason (R) : Electrons are entering $5 f$ orbitals in actinoids which experience greater shielding from nuclear charge. In the light of the above statements, choose the correct answer from the options given below:

  • Correct answer
    A
    Both $(\mathbf{A})$ and $(\mathbf{R})$ are true and $(\mathbf{R})$ is the correct explanation of $(\mathbf{A})$.
  • B
    Both $(\mathbf{A})$ and $(\mathbf{R})$ are true but $(\mathbf{R})$ is not the correct explanation of $(\mathbf{A})$.
  • C
    (A) is true but (R) is false.
  • D
    (A) is false but $(\mathbf{R})$ is true.

Solution

Ionisation enthalpies of early actinoids are lower than early lanthanoids. This is because $5 f$ orbitals will penetrate less into the inner core of electrons. The $5 f$ electrons, will be more effectively shielded from the nuclear charge than the $4 f$ electrons of corresponding lanthanoids.

Hence, the correct answer is option: 'A'.

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