Q5 / 90 · JEE Main 2021 (26 Aug Shift 2) · Chemistry

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Heavy water is used for the study of reaction mechanism.
Reason (R): The rate of reaction for the cleavage of O-H bond is slower than that of O-D bond.
Choose the most appropriate answer from the options given below :

  • A
    Both (A) and (R) are true and (R) is the true explanation of (A).
  • Correct answer
    B
    (A) is true but (R) is false.
  • C
    (A) is false but (R) is true.
  • D
    Both (A) and (R) are true but (R) is not the true explanation of (A).

Solution

Statement-1: D2O is used as a moderator in nuclear reactor and in exchange reactions for the study of reaction mechanisms.
Statement-2 : Bond energy of O-H< Bond energy of O-D.
So rate of reaction of cleavage of O-H bond is faster than that of O-D bond.

Hence, the correct answer is option: 'B'.

More Hydrogen Questions