Q1 / 90 · JEE Main 2021 (26 Aug Shift 2) · Chemistry

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): Barium carbonate is insoluble in water and is highly stable.
Reason (R): The thermal stability of the carbonates increases with increasing cationic size.
Choose the most appropriate answer from the options given below :

  • A
    (A) is true but (R) is false.
  • Correct answer
    B
    Both (A) and (R) are true.
  • C
    (A) is false but (R) is true.
  • D
    Both (A) and (R) are false.

Solution

Figure

(i) Stability ↑ as size of cation ↑, ionic character ↑

(ii) Solubility in water ↓

Hence, the correct answer is option: 'B'.

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