Q53 / 180 · KCET 2017 · Chemistry

Gabriel phthalimide synthesis is used in thepreparation of primary amine fromphthalimide,
which of the following reagent isnot used during the process?

  • A
    \( \mathrm{KOH} \)
  • B
    \( \mathrm{NaOH} \)
  • Correct answer
    C
    \( \mathrm{HCl} \)
  • D
    Alkyl Halides

Solution

This reaction is used to prepare primary amines. In this reaction, phthalimide is converted it to potassium salt by heating
with alcoholic \( \mathrm{KOH} \). The salt is then treated with alkyl halide to give \( \mathrm{N} \)-alkyl phthalimide, which on alkaline hydrolysis with
aqueous \( \mathrm{NaOH} \) gives a primary amine as the product.
Figure
Phthalimide
Figure
Figure
Phthalic acid Ethyl amine

Hence, the correct answer is option: 'C'.

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