Q23 / 75 · JEE Main 2026 (04 April Shift 1) · Chemistry
$2.0$ g of a bromo hydrocarbon $(X)$ was subjected to Carius analysis, gave $3.36$ g of $AgBr$. The percentage of carbon in the compound $(X)$ is $26.7\%$. Total number of carbon atoms in the empirical formula for compound $(X)$ is _____. (Given molar mass in g mol$^{-1}$ H:$1$, C:$12$, Br:$80$, Ag:$108$)
Correct answer: 5
Solution
Mass of $AgBr$ formed = $3.36$ g
Molar mass of $AgBr = 108 + 80 = 188$ g mol$^{-1}$
Moles of $AgBr$ formed = $\dfrac{3.36}{188} \approx 0.01787$ mol
Since $1$ mole of $AgBr$ contains $1$ mole of $Br$, moles of $Br$ in the compound = $0.01787$ mol.
Mass of $Br = 0.01787 \times 80 = 1.43$ g
Percentage of $Br$ in compound $(X) = \dfrac{1.43}{2.0} \times 100 = 71.5\%$
Given percentage of $C = 26.7\%$
Percentage of $H = 100\% - (71.5\% + 26.7\%) = 1.8\%$
Now, we find the molar ratio of the elements in the compound:
Moles of $C = \dfrac{26.7}{12} = 2.225$
Moles of $H = \dfrac{1.8}{1} = 1.8$
Moles of $Br = \dfrac{71.5}{80} = 0.893$
Dividing by the smallest value ($0.893$) to get the simplest ratio:
$C : H : Br = \dfrac{2.225}{0.893} : \dfrac{1.8}{0.893} : \dfrac{0.893}{0.893}$
$C : H : Br \approx 2.5 : 2 : 1$
Multiplying by $2$ to obtain whole numbers, we get the ratio $5 : 4 : 2$.
The empirical formula of the compound is $C_5H_4Br_2$.
The total number of carbon atoms in the empirical formula is $5$.
Answer: $5$
Molar mass of $AgBr = 108 + 80 = 188$ g mol$^{-1}$
Moles of $AgBr$ formed = $\dfrac{3.36}{188} \approx 0.01787$ mol
Since $1$ mole of $AgBr$ contains $1$ mole of $Br$, moles of $Br$ in the compound = $0.01787$ mol.
Mass of $Br = 0.01787 \times 80 = 1.43$ g
Percentage of $Br$ in compound $(X) = \dfrac{1.43}{2.0} \times 100 = 71.5\%$
Given percentage of $C = 26.7\%$
Percentage of $H = 100\% - (71.5\% + 26.7\%) = 1.8\%$
Now, we find the molar ratio of the elements in the compound:
Moles of $C = \dfrac{26.7}{12} = 2.225$
Moles of $H = \dfrac{1.8}{1} = 1.8$
Moles of $Br = \dfrac{71.5}{80} = 0.893$
Dividing by the smallest value ($0.893$) to get the simplest ratio:
$C : H : Br = \dfrac{2.225}{0.893} : \dfrac{1.8}{0.893} : \dfrac{0.893}{0.893}$
$C : H : Br \approx 2.5 : 2 : 1$
Multiplying by $2$ to obtain whole numbers, we get the ratio $5 : 4 : 2$.
The empirical formula of the compound is $C_5H_4Br_2$.
The total number of carbon atoms in the empirical formula is $5$.
Answer: $5$
Hence, the correct answer is 5.