Q24 / 90 · JEE Main 2023 (31 Jan Shift 1) · Chemistry

For reaction: SO2( g)+12O2( g)⇌SO3( g) KP=2×1012 at 27°C and 1 atm pressure. The Kc for the same reaction is ×1013.( Nearest integer)
(Given R=0.082 L atm K-1 mol-1 )

Correct answer: 1

Solution

For reaction: SO2(g) + 12O2(g) ⇌ SO3(g)

Kp = 2×1012 at 300 K and 1 atm pressure.

The relation between equilibrium constant in terms of pressures Kp and equilibrium constant in terms of concentration Kc is

Kp = Kc × (RT)∆ng

⇒ 2×1012 = Kc × (0.082 × 300)-12

⇒ KC= 9.92 × 1012

⇒ KC = 0.992 × 1013

So, answer is 1.

Hence, the correct answer is 1.

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